(Z)-N-{3-[(6-Chloro­pyridin-3-yl)meth­yl]-1,3-thia­zolidin-2-yl­idene}cyanamide

نویسندگان

  • Jin-Sheng Gao
  • Jun Qiao
  • Ying-Hui Yu
  • Guang-Feng Hou
چکیده

The asymmetric unit of the title compound, C(10)H(9)ClN(4)S, common name thia-cloprid, comprises two mol-ecules. In both mol-ecules, the thia-zolidine rings are almost planar (with r.m.s. deviations of 0.016 and 0.065 Å) and form dihedral angles of 73.36 (6) and 70.25 (8)° with the 2-chloro-pyridine rings. In the crystal, inter-molecular C-H⋯N hydrogen bonds links the mol-ecules into chains propagating in [[Formula: see text]01].

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منابع مشابه

(Z)-N-{3-[(2-Chloro-1,3-thia­zol-5-yl)meth­yl]-1,3-thia­zolidin-2-yl­idene}cyanamide

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(Z)-N-(3-Nicotinoyl-1,3-thia­zolidin-2-yl­idene)cyanamide

In the title compound, C(10)H(8)N(4)OS, the dihedral angle between the pyridine and thia-zolidine rings is 52.5 (5)°. Inter-molecular C-H⋯N inter-actions help to stabilize the crystal structure.

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(E)-2-{1-[(6-Chloro­pyridin-3-yl)meth­yl]imidazolidin-2-yl­idene}-2-cyano-N-(2-methylphenyl)acetamide

In the title compound, C(19)H(18)N(5)O, the imidazolidine ring makes dihedral angles of 87.62 (17) and 28.27 (11)° with the pyridine and benzene rings, respectively. An intra-molecular N-H⋯O hydrogen bond is observed between the carbonyl O atom and an imidazolidine H atom. In the crystal, an inter-molecular N-H⋯N hydrogen bond gives rise to a linear chain running along the b axis.

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عنوان ژورنال:

دوره 67  شماره 

صفحات  -

تاریخ انتشار 2011